{"id":3470,"date":"2026-05-18T06:49:11","date_gmt":"2026-05-18T13:49:11","guid":{"rendered":"https:\/\/coherencegeometry.com\/?p=3470"},"modified":"2026-05-18T08:24:39","modified_gmt":"2026-05-18T15:24:39","slug":"atomic-orbitals-via-coherence-geometry","status":"publish","type":"post","link":"https:\/\/coherencegeometry.com\/index.php\/2026\/05\/18\/atomic-orbitals-via-coherence-geometry\/","title":{"rendered":"Atomic Orbitals via Coherence Geometry"},"content":{"rendered":"\n<p class=\"wp-block-paragraph\"><strong>Internal ID:<\/strong> CGI-RSR-000024<br><strong>Author(s):<\/strong> Barry L. Petersen<br><strong>Document Type:<\/strong> Research Paper<br><strong>Publication Date:<\/strong> May 2026<br><strong>Original Creation Date:<\/strong> September 7, 2025<br><strong>Revised Document Date:<\/strong> N\/A<br><strong>Status:<\/strong> Public<br><strong>Domains:<\/strong> Chemistry, Physics<br><strong>Sub-Domain:<\/strong> Quantum Chemistry<br><strong>Research Topics:<\/strong> Atomic orbitals, orbital morphogenesis, nodal topology<\/p>\n\n\n\n<h3 class=\"wp-block-heading\">Abstract<\/h3>\n\n\n\n<p class=\"wp-block-paragraph\"><br>This paper introduces a geometric framework for the spontaneous emergence of atomic orbital structures from curvature-driven field dynamics, independent of quantum mechanical postulates. Within Petersen\u2019s Coherence Geometry (CG) framework, orbitals arise as metastable attractors in a real-valued amplitude field, shaped by angular tension gradients and curvature bifurcations. Starting from isotropic initial conditions, the system evolves toward familiar nodal geometries such as \\(p_x\\), \\(p_z\\), \\(d_{z^2}\\), \\(f_{z^3}\\), and \\(g_{z^4}\\)\u2014all without imposing eigenfunction bases, boundary constraints, or complex-valued wavefunctions. The resulting orbital shapes are not approximations or heuristic visualizations, but precise topological equivalents of those derived from the Schr\u00f6dinger equation. Each configuration reproduces the correct number, orientation, and type of nodal surfaces expected for its orbital class. By encoding phase relationships and spatial distortion through geometric tension, the CG framework offers a physically grounded alternative to conventional orbital theory\u2014unifying orbital formation and structure under a single real-valued dynamical principle. These results suggest the existence of a deeper geometric substrate underlying orbital identity\u2014one in which nodal topology emerges not from imposed quantization, but from the spontaneous self-organization of curvature fields. This approach provides a new lens for understanding atomic structure and may lay the groundwork for extending geometric methods into bonding, spin, and unified field modeling.<\/p>\n\n\n\n<h3 class=\"wp-block-heading\">Representative Figure<\/h3>\n\n\n\n<div style=\"height:12px\" aria-hidden=\"true\" class=\"wp-block-spacer\"><\/div>\n\n\n<style>.kb-image3470_ac32da-8b .kb-image-has-overlay:after{opacity:0.3;border-top-left-radius:10px;border-top-right-radius:10px;border-bottom-right-radius:10px;border-bottom-left-radius:10px;}.kb-image3470_ac32da-8b img.kb-img, .kb-image3470_ac32da-8b .kb-img img{border-top:2px solid var(--global-palette5, #4A5568);border-right:2px solid var(--global-palette5, #4A5568);border-bottom:2px solid var(--global-palette5, #4A5568);border-left:2px solid var(--global-palette5, #4A5568);border-top-left-radius:10px;border-top-right-radius:10px;border-bottom-right-radius:10px;border-bottom-left-radius:10px;box-shadow:10px 10px 30px 0px rgba(0, 0, 0, 0.2);}@media all and (max-width: 1024px){.kb-image3470_ac32da-8b img.kb-img, .kb-image3470_ac32da-8b .kb-img img{border-top:2px solid var(--global-palette5, #4A5568);border-right:2px solid var(--global-palette5, #4A5568);border-bottom:2px solid var(--global-palette5, #4A5568);border-left:2px solid var(--global-palette5, #4A5568);}}@media all and (max-width: 767px){.kb-image3470_ac32da-8b img.kb-img, .kb-image3470_ac32da-8b .kb-img img{border-top:2px solid var(--global-palette5, #4A5568);border-right:2px solid var(--global-palette5, #4A5568);border-bottom:2px solid var(--global-palette5, #4A5568);border-left:2px solid var(--global-palette5, #4A5568);}}<\/style>\n<figure class=\"wp-block-kadence-image kb-image3470_ac32da-8b size-medium_large\"><img loading=\"lazy\" decoding=\"async\" width=\"768\" height=\"403\" src=\"https:\/\/coherencegeometry.com\/wp-content\/uploads\/2025\/12\/Orbital_Linear_Combo_2_Layer_Off_White_1200x630_96_dpi-768x403.png\" alt=\"\" class=\"kb-img wp-image-1473\" srcset=\"https:\/\/coherencegeometry.com\/wp-content\/uploads\/2025\/12\/Orbital_Linear_Combo_2_Layer_Off_White_1200x630_96_dpi-768x403.png 768w, https:\/\/coherencegeometry.com\/wp-content\/uploads\/2025\/12\/Orbital_Linear_Combo_2_Layer_Off_White_1200x630_96_dpi-300x158.png 300w, https:\/\/coherencegeometry.com\/wp-content\/uploads\/2025\/12\/Orbital_Linear_Combo_2_Layer_Off_White_1200x630_96_dpi-1024x538.png 1024w, https:\/\/coherencegeometry.com\/wp-content\/uploads\/2025\/12\/Orbital_Linear_Combo_2_Layer_Off_White_1200x630_96_dpi-600x315.png 600w, https:\/\/coherencegeometry.com\/wp-content\/uploads\/2025\/12\/Orbital_Linear_Combo_2_Layer_Off_White_1200x630_96_dpi.png 1200w\" sizes=\"auto, (max-width: 768px) 100vw, 768px\" \/><\/figure>\n\n\n\n<div style=\"height:11px\" aria-hidden=\"true\" class=\"wp-block-spacer\"><\/div>\n\n\n\n<p class=\"has-text-align-center wp-block-paragraph\"><em>Spontaneous emergence of atomic orbital structures from curvature-driven field dynamics<\/em> <\/p>\n\n\n\n<h3 class=\"wp-block-heading\">Available Document<\/h3>\n\n\n\n<p class=\"wp-block-paragraph\"><strong>DOI:<\/strong> <code>10.5281\/zenodo.20270492<\/code><\/p>\n\n\n\n<p class=\"wp-block-paragraph\"><strong>Citation:<\/strong><br>Petersen, B. L. (2026). Atomic Orbitals via Coherence Geometry. Zenodo. <a href=\"https:\/\/doi.org\/10.5281\/zenodo.20270492\" rel=\"nofollow noopener\" target=\"_blank\">https:\/\/doi.org\/10.5281\/zenodo.20270492<\/a><\/p>\n\n\n\n<h3 class=\"wp-block-heading\">Source Code and Supporting Materials<\/h3>\n\n\n\n<p class=\"wp-block-paragraph\">Simulation code is not included in this release. The simulations and visual outputs are reported in the paper, but the underlying computational notebooks and scripts are internal research artifacts and are not packaged as public software. No public technical support is implied.<\/p>\n\n\n\n<h3 class=\"wp-block-heading\">Summary and Notes<\/h3>\n\n\n\n<p class=\"wp-block-paragraph\"><em>Core result:<\/em><br>Starting from isotropic or minimally structured initial conditions, the CG relaxation process produces recognizable nodal orbital geometries without inserting standard quantum-mechanical orbital equations directly. The resulting forms reproduce key topological features associated with conventional orbital classes, including nodal number, orientation, and surface type.<\/p>\n\n\n\n<p class=\"wp-block-paragraph\"><em>Scope:<\/em><br>This document should be read as a geometric and simulation-driven CG formulation of orbital morphogenesis. It focuses on the emergence of orbital identity and nodal topology from coherence-geometric relaxation, rather than on a complete quantitative treatment of all electronic-structure phenomena. Broader chemistry-scale modeling, spectral calibration, and predictive computational chemistry applications are left to future work.<\/p>\n\n\n\n<p class=\"wp-block-paragraph\"><em>Historical and framework context:<\/em><br>This paper is released in its original September 2025 form. It belongs to the early simulation-driven chemistry phase of the Coherence Geometry research corpus, before the later canon records and Foundations texts were fully organized. Some internal references reflect the framework references available at the time of writing. Later canon and Foundations materials provide the current public reference layer for the underlying CG formalism.<\/p>\n\n\n\n<p class=\"wp-block-paragraph\"><em>Relation to later work:<\/em><br>This orbital paper is paired conceptually with later CG chemistry work on atomic bonding, where orbital-like coherence structures are allowed to interact and form bond-like configurations. The present paper focuses on orbital identity and morphogenesis; the bonding paper develops interaction and structural coupling between such forms.<\/p>\n\n\n\n<h3 class=\"wp-block-heading\">Related Work<\/h3>\n\n\n\n<p class=\"wp-block-paragraph\">Petersen, B. L. (2026). A Multi-Phase Extension of Complex Numbers and the Global Coherence Theorem. Zenodo.&nbsp;<a href=\"https:\/\/doi.org\/10.5281\/zenodo.20116654\" rel=\"nofollow noopener\" target=\"_blank\">https:\/\/doi.org\/10.5281\/zenodo.20116654<\/a><\/p>\n\n\n\n<p class=\"wp-block-paragraph\">Petersen, B. L. (2026). Mathematical Foundations of Coherence Formation and Stability. Zenodo.&nbsp;<a href=\"https:\/\/doi.org\/10.5281\/zenodo.20116648\" rel=\"nofollow noopener\" target=\"_blank\">https:\/\/doi.org\/10.5281\/zenodo.20116648<\/a><\/p>\n\n\n\n<p class=\"wp-block-paragraph\">Petersen, B. L., &amp; Johnson, R. K. (2026). A Variational\u2013Relaxation Framework for Coherence-Driven Structure Formation. Zenodo.&nbsp;<a href=\"https:\/\/doi.org\/10.5281\/zenodo.20120588\" rel=\"nofollow noopener\" target=\"_blank\">https:\/\/doi.org\/10.5281\/zenodo.20120588<\/a><\/p>\n\n\n\n<p class=\"wp-block-paragraph\">Petersen, B. L. (2026). Coherence Geometry Foundations, Part I: Orientation,<br>Closure, and Algebraic Foundations (Version 0.1). Zenodo.<br><a href=\"https:\/\/doi.org\/10.5281\/zenodo.20156532\" rel=\"nofollow noopener\" target=\"_blank\">https:\/\/doi.org\/10.5281\/zenodo.20156532<\/a><\/p>\n\n\n\n<p class=\"wp-block-paragraph\">Petersen, B. L. (2026). Coherence Geometry Foundations, Part II: Physical<br>Projections (Version 0.1). Zenodo.<br><a href=\"https:\/\/doi.org\/10.5281\/zenodo.20156997\" rel=\"nofollow noopener\" target=\"_blank\">https:\/\/doi.org\/10.5281\/zenodo.20156997<\/a><\/p>\n\n\n\n","protected":false},"excerpt":{"rendered":"<p>CGI-RSR-000024 | This paper introduces a geometric framework for the spontaneous emergence of atomic orbital structures from curvature-driven field dynamics, independent of quantum mechanical postulates. Within Petersen\u2019s Coherence Geometry (CG) framework, orbitals arise as metastable attractors in a real-valued amplitude field, shaped by angular tension gradients and curvature bifurcations.<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_kad_post_transparent":"","_kad_post_title":"","_kad_post_layout":"","_kad_post_sidebar_id":"","_kad_post_content_style":"","_kad_post_vertical_padding":"","_kad_post_feature":"","_kad_post_feature_position":"","_kad_post_header":false,"_kad_post_footer":false,"_kad_post_classname":"","footnotes":""},"categories":[71,32,31,68,56],"tags":[],"class_list":["post-3470","post","type-post","status-publish","format-standard","hentry","category-quantum-chemistry","category-chemistry","category-physics","category-quantum-foundations","category-research-papers"],"_links":{"self":[{"href":"https:\/\/coherencegeometry.com\/index.php\/wp-json\/wp\/v2\/posts\/3470","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/coherencegeometry.com\/index.php\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/coherencegeometry.com\/index.php\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/coherencegeometry.com\/index.php\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/coherencegeometry.com\/index.php\/wp-json\/wp\/v2\/comments?post=3470"}],"version-history":[{"count":5,"href":"https:\/\/coherencegeometry.com\/index.php\/wp-json\/wp\/v2\/posts\/3470\/revisions"}],"predecessor-version":[{"id":3528,"href":"https:\/\/coherencegeometry.com\/index.php\/wp-json\/wp\/v2\/posts\/3470\/revisions\/3528"}],"wp:attachment":[{"href":"https:\/\/coherencegeometry.com\/index.php\/wp-json\/wp\/v2\/media?parent=3470"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/coherencegeometry.com\/index.php\/wp-json\/wp\/v2\/categories?post=3470"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/coherencegeometry.com\/index.php\/wp-json\/wp\/v2\/tags?post=3470"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}